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The existence of certain Si– and C– dangling bonds is believed to be the origin of tritium trapping and retarded diffusion.
Also, the presence of WC particles resulted in coatings with enhanced microhardness values and retarded diffusion phenomena in the deposits during thermal treatment.
Equal distribution of immobilized probe, however, does not eliminate retarded diffusion.
The observation of the calcite single crystals using atomic force microscopy revealed that the inhibitory effect was attributed to the retarded diffusion of fluoride to the calcite surface, which was also in accordance with the analysis of bulk experiments with calcite powders.
From the experimental observations, the effect of the pressure on these micro-structural and compositional evolutions was considered in two ways: the retarded diffusion of the alloying elements under high pressure and the volume difference between γ′ precipitates and the γ matrix.
Modifications in gel element manufacturing processes may make the gel interior more accessible and "solution-like," mitigating the retarded diffusion described above.
Similar(51)
This indicates that a combination of the S/GNS composite cathode and PVDF-HFP/PMMA/SiO2 GPE plays a significant role of retarding diffusion of the polysulfides out of the cathode area and suppressing their transport towards the anode side (shuttle effect).
Thirdly, the adsorbed SO forms a compact inhibition film, which would further retard diffusion and approach of water, oxygen and aggressive species to the surface.
Such transient interactions would be expected to retard diffusion.
We can state however that it is not slowed so much as to retard diffusion at timescales commonly used in processing of BHJs, that is, minutes.
These characteristic diffusion times represent a lower boundary, as interactions with the LPRTG-gel substrate would be expected to retard diffusion and create gradients in reaction rate during the 1 h incubation.
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