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The mean free volume hole size (Vf) values were calculated from the positron lifetime data.

Addition of salt from 10 to 45 wt% LiTf resulted in an increase in the mean free volume cavity size at room temperature (r.t).

When considering simple binary interchain interaction, the mean free volume hole fraction in a blend was computed in terms of an interaction parameter that might be correlated to the Flory–Huggins interaction parameter.

From the PALS data the glass transition temperature, Tg, decreases (from 382 to 224 ± 5 K) and a given mean free volume is observed at lower temperatures as the side-chain length increases (going from methyl- to hexyl-).

The addition of low molecular weight plasticizers to the polyether-urethane results in a constant or decreasing mean free volume cavity radius, as measured by the orthoPositronium lifetime τ3, and a decreasing relative concentration of free volume cavities as measured by the ortho-Positronium intensity, I3.

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Mean free volumes radii and fractional free volumes have been calculated from the lifetime data.

At the bulk scale, small values of strain do not affect thermal conductivity, but this may not true for grain sizes comparable with the electron and phonon mean free paths and for higher volume fraction of grain boundaries.

As the particle volume fraction increases, the dislocation mean free path length and average distance between dislocations obstacles can be significantly reduced, implying enhancement of strength.

The effects of particle distribution pattern, particle size, shape and volume fraction on the dislocation mean free path length and average obstacle distance are analyzed in two- and three-dimensional models.

In Figs. 4(a) and (b) we plot the maximum amplitude in the focal volume as a function of slab thickness normalized with respect to the (a) transport mean free path l* and (b) single scattering mean free path l s, respectively.

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