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Teachers and school librarians: Please note that if your group entry consists of more than 4 reviews, you will need to send them in via email to [email protected].
Please note that if your group entry consists of more than four reviews, you will need to send them in via email to [email protected] (you can also ask any questions about the comp using this email address).
However, there was no pre-selection in terms of group entry.
Generally, high yields of imine products are attainable, although substrates with a strongly electron-withdrawing para-substituent group (entry 9) are less reactive, thus mirroring MAO B reactivity trends.
Glycosylation of the l-rhamnal 10, which lacks the cyclic protecting group, with 3 a (entry 5) yielded the disaccharide 12 with a lower α/β (4:1) ratio than that obtained with the trans-fused cyclic protecting group (entry 1), thus further highlighting the effect of the constraint on the l-rhamnal glycosylation stereo-outcome.
Despite our success with the phenyl group transfer, cross-coupling reactions to install a methyl group (entry 3) were less efficient, with a moderate yield of 39% achievable using methylboronic acid (the reaction with trimethylboroxine gave no product), although importantly, it eliminated the need to handle tetramethyl stannane.
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For school group entries submitted by post, please ensure the form and reviews are sent as one submission in a single envelope.
In addition, there are group entries on pre-Raphaelite female artists and female artists in Ruskin's circle.
Protein group entries with a normalized ratio significance B score of ≤ 0.05 or significance A score of ≤ 0.05 were retained for further analysis.
A significant increase in the rate of the reaction could be observed when more than one electron donating groups (entry 11, 12 and 13) are present.
Importantly, the method tolerates functional groups that are typically reduced under single-electron-transfer conditions, including aromatic rings (entries 4 and 5), ethers (entry 6), trifluoromethyl groups (entry 7), and halides (entry 8).
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