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Importantly, the nanoporous Mo2C functionalized anode is revealed for the first time to have unique electrocatalytic activity towards redox reaction of flavins with more negative redox potential, indicating a more favourable thermodynamic driving force for anodic electron transfer.
It has a more negative redox potential than DOX (−450 mV) and has no cardiotoxicity as a result.
The presence of a water molecule bound to the ferrous heme has been shown to correlate with a more negative redox potential in myoglobin His64(E7) mutants.
The mitochondrial matrix NAD operates at a more negative redox potential (86), −318 mV, providing a greater reductive force for mitochondrial ATP production.
The [NADPH]/[NADP+] system is equilibrated with NADP-linked dehydrogenases and operates at a more negative redox potential than the NAD system, that is, −393 mV in the cytosol and −415 mV in the mitochondrial matrix (Fig. 2B) (100).
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A yeast model system studied with a fluorescence imaging probe (71) showed a substantially more negative GSH redox potential (very low free GSSG); the relevance for mammalian cell physiology will need to be addressed.
In a hypothetical scenario in which the redox potential constitutes the sole driving force of the reaction, the more negative the heme redox potential, the faster the heme autoxidation (and concomitant oxygen reduction).
The HOMO level of sensitizer must be more negative than the redox potential with respect to the vacuum level in the range of 0.2 0.3 eV [26].
It was already reported that the conduction band of UiO-66 was −0.6 V vs. normal hydrogen electrode (NHE), and this is more negative than the redox potential of H+/H2 −0.4 V vs. NHE, pH = 7).
Secondly, the conduction bands consisting of Nb4d orbitals located at a more negative state of redox potential of H+/H2 promote the separation and transfer of photo-induced charge carriers and result in high photocatalytic activities [13].
Generally, H2O splitting requires the bottom level of the conduction band to be more negative than the redox potential of H+/H2 (0 V vs. NHE), while the top level of the valence band should be more positive than the redox potential of H2O/O2 (1.23 V vs. NHE).
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more negative connotation
more negative material
more negative cathodic
more stable redox
more favorable redox
more efficient redox
more reversible redox
more negative attention
more detailed redox
more negative publicity
more nonprotein redox
more oxidizing redox
more noble redox
more negative climate
more complex redox
more complicated redox
more negative energy
more positive redox
more negative analyst
more oxidized redox
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