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We demonstrate that a more efficient redox hydrogel structure can be achieved by engineering the size and the surface charge of the bioelectrocatalyst.
In spite of their micrometric size, SA stars are nanostructured and have finer crystallite size: this entails a much higher BET area, greater availability of oxygen vacancies, more efficient redox cycles and, therefore, a higher oxidative capability.
DMNQ is a more efficient redox cycling agent than DOX but unlike DOX has limited ability to inhibit gene transcription and DNA replication.
This suggests that 13 in some way enables more efficient redox cycling, and we note in this regard that copper(I) thiocyanate is a p-type semiconductor.
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The higher NADPH/NADP+ ratio indicated gapN-encoding GAPDN was more efficient to modulate redox status.
The development of more efficient electrode materials is essential to obtain vanadium redox flow batteries (VRFBs) with enhanced energy densities and to make these electrochemical energy storage devices more competitive.
More efficient DET can be obtained by introducing a redox center into more hydrophobic regions far from aqueous environment, thus lowering the reorganization energy.
This improvement is very likely due to a more efficient hydrogel structure rather than a better intrinsic electron transfer between the FAD/FADH2 redox center and the redox mediator.
Platinum catalysts were more efficient than gold ones, which was ascribed to their superior redox properties.
While prokaryotes have the advantage that their simpler cell membranes and internal structure are more amenable for physical electron extraction, the more complex metabolism of eukaryotes may be more efficient and be able to support a larger diversion of redox carrier flux without undue harmful effects on the organism.
This review discusses different approaches to enhance the sensitivity and selectivity of CDH-based biosensors, which focus on (1) more efficient DET on chemically modified or nanostructured electrodes, (2) the synthesis of custom-made redox polymers for higher MET currents and (3) the engineering of enzymes and reaction pathways.
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