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In the course of the work, three different model versions were mapped.
Both model versions were newly implemented and calibrated using routinely collected field ratings of phenological stages of winter wheat crops.
Two model versions were considered differing between each other by the formulation of the oceanic uptake of carbon dioxide and by the governing parameters of the terrestrial carbon uptake module.
Two model versions were set up: (1) a simplified large scale model to evaluate the long-term reaction zoning to be expected due to permanent oxygen gas injection, and (2) a verification of the monitored hydrochemistry during a first field test performed near the contamination source.
Four different model versions were compared here, based on the Akaike Information Criterion (AIC) [ 25, 26].
In order to assess the value of the stochastic aspect of the model, deterministic model versions were also built.
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Usually, in the course of a modeling project many unsuccessful model versions are tested but only the successful one is finally published.
The total number of data points, residual means and root mean squared (rms) values of the two model versions are listed in Table 1.
Coefficients and data sets for the CHAOS-3 α and CHAOS-3 model versions are available at www.space.dtu.dk/files/magnetic-models/CHAOS-3/.
Calibration for all parameters of both model versions was done using a step by step procedure thereby using different methods for parameter identification.
However, using the study case of an agricultural intensive irrigated watershed, it was shown that all the model versions are not able to appropriately reproduce the total streamflow in such system when the irrigation source is outside the watershed.
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