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Moreover a noticeable mobility of amorphous PEG segments and the presence of mobile isolated or loosely packed PE segments in all-trans conformations have been highlighted in PE-PEG/SiO2 hybrids.
The aggregation between the microspheres might be stimulated by high mobility of amorphous regions of PLLA on the microsphere surfaces since both water vapor and gas mixture can reduce glass transition temperature (Tg) of PLLA below the sterilization temperature.
The study confirmed the generality of a one-to-one correlation between the oxygen permeability of BOPP films and the mobility of amorphous tie chains as measured by the intensity of the dynamic mechanical β-relaxation.
The higher values of wraf also appear to result in higher values of the glass transition temperature (Tg) for melt crystallized samples due to a reduction in mobility of amorphous phase.
They exhibit metal-oxide-semiconductor field effect transistor mobility of 10 12 cm2 V−1 s−1 at room temperature, which is comparable to previous reported mobility of amorphous carbon.
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However, we would like to emphasize that these issues of mobility extraction do not question the general conclusion of section 3 that there is now a broad range of organic semiconductors that significantly exceed mobilities of amorphous silicon.
We interpret these results assuming that the restriction to the mobility of the amorphous phase occurs mainly in the amorphous regions between the lamellar stacks and not in the amorphous regions within the lamellar stacks.
ATR observations suggest that these exposures increase the mobility of the amorphous content.
The chain mobility of matrix amorphous portion plays a dominant role on toughening.
The hardness increase is explained in terms of the large reduction in molecular mobility of the amorphous, interlamellar layers.
DMTA analysis shows a marginal lowering of the Tg and an increased mobility of the amorphous phase.
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