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The maximum discharge capacities of the two low-Co alloys can reach 307 mAh/g for AB4.8 alloy and 298 mAh/g for AB4.6 alloy, respectively.
Galvanostatic discharge-charge tests indicate maximum discharge capacities of 152 mA h g−1 when the material is treated at 700 °C for 15 minutes.
The examination of the variation of discharge capacity as function of the cycle number (Fig. 3) reveals that the alloys possess good activation performances, attaining their maximum discharge capacities at the first cycle.
The HFSC anode of desirable physiochemical properties delivers the maximum discharge capacities of 1106.9 and 616.9 mAhg−1 at low and high current densities of 100 and 1100 mAg−1, respectively.
The maximum discharge capacities of the alloy electrodes increase from 244.6 mAh/g (x = 0) to 380 mAh/g (x = 1.0), and then decrease to 353.6 mAh/g (x = 1.3).
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The electrochemical tests show that maximum discharge capacity, high rate dischargeability (HRD), dischargeability at low temperature and cyclic stability was improved by vacuum evaporation plating Cu, Al and Ni.
Due to variation in phases of the alloys, the maximum discharge capacity, the high rate dischargeability (HRD), and the low temperature dischargeability increase first and then decrease.
The maximum discharge capacity and high-rate dischargeability of milled alloy electrodes were obviously higher than those of the alloy electrode before milling.
The maximum discharge capacity and the high rate dischargeability (HRD) of La0.7Mg0.3Ni2.875Co0.525Mn0.1 alloy electrode both decrease with decreasing test temperature, mainly due to the slower hydrogen transfer in the bulk of the alloy and the lower electrocatalytic activity at lower temperatures.
The maximum discharge capacity and the high-rate dischargeability (HRD) of the La0.75 Mg0.25Ni3.5 alloy electrode both decrease with decreasing testing temperature, which mainly due to the slower hydrogen transfer in the bulk of the alloy and the lower electrocatalytic activity at lower temperatures.
Compared with bare hydrogen storage alloys, the fabricated composite shows larger maximum discharge capacity, 326.37 vs. 302.62 mAh g−1, and enhanced high rate dischargeability with larger discharge capacity at a current density of 3000 mA g−1, 59.01 vs. 40.88 mAh g−1.
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maximum discharge power
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increased discharge capacities
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