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This work brings in a new feature of an "optimum" pore radius for maximum adsorption rate in polymeric systems.
Under the test conditions used here, a 5 cm bed thickness is recommended with a maximum adsorption rate of 473 g/h.
The results show that maximum adsorption rate is with the sample having 37%% concentration of CaCl2, which is 0.1 kg/h.
By applying the model, the maximum adsorption rate (r ads_max) has been calculated and the resulting data are presented in Table 4.
According to the R 2 values in this table, it can be observed that, in the three set of experiments carried out, the linear models explain more than 95% of the variance found in the maximum adsorption rate data.
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The maximum adsorption occurs at stirring rate of 150 rpm, and thereafter, the adsorption is almost constant.
In order to investigate the adsorption rate and maximum adsorption capacity, the experimental data were fitted to Langmuir, Freundlich, Temkin, Redlich Peterson and Sips isotherms and pseudo first-order, pseudo second-order and intraparticle diffusion kinetic models.
The maximum adsorption capacity (Qm) and constant rate were found 0.318 (mg/g) and 0.21 (mg/g.min), respectively.
Adsorption rate reached a maximum value between 30 and 42°C.
Batch kinetic and equilibrium experiments were conducted to determine the adsorption kinetic rate constants and maximum adsorption capacities.
Prediction of the adsorption rate and the maximum sorption bed capacity can be determined by applying certain mathematical models (Vaňková et al. 2010; Unuabonah et al. 2010).
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