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Successive thermal curing produces a stabilisation of the macroscopic orientation of the liquid crystalline network.
We show that a uniform macroscopic orientation of the mesogenic groups in SCLCPs can easily be achieved upon elongation of the films.
The structural evolution is hierarchical as the structural variations have their cause in a different macroscopic orientation of the cementite in the initial (patented) structure with respect to the wire axis.
More interestingly, a suitable thermal treatment of the deformed films can result in relaxed, free standing films which have almost the initial length before stretching, and in which the stretching-induced macroscopic orientation of the mesogenic groups is retained.
Macroscopic orientation of the liquid crystalline epoxy resins (LCERs) was achieved by curing in a high strength magnetic field, and quantified by an orientation parameter determined with wide angle X-ray diffraction.
In this paper, we show that mechanically stretching an immiscible blend made from a nematic side-chain liquid crystalline polymer and a conventional polymer is an efficient way to induce a rapid macroscopic orientation of the mesogenic groups along the stretching direction.
Similar(54)
We conclude that our bicelle samples indeed confer macroscopic orientation to cytochrome b5, and that by different NMR pulse schemes, we can distinguish domains of cytochrome b5 that display different degrees of molecular mobility.
A unique macroscopic orientation and preloading of the seta increased attachment force 600-fold above that of frictional measurements of the material.
However, the width and overall shape of the lines indicates that only a very limited amount of macroscopic orientation is reached.
The mechanically induced macroscopic orientation in two series of side-chain liquid crystalline ionomers was investigated in order to reveal the effects of the ionic aggregates.
The macroscopic orientation parallel to the faces of the dry films and the short-range ordering in the direction perpendicular to the faces was observed.
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