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In graphene, the phonon energy shift caused by laser excitation creates three main peaks known as G band (peak: ~1580 cm−1), D band (peak: ~1350 cm−1), and 2D band (peak: ~2700 cm−1) [47].
A 2D band peak at 2,692 cm-1 and a G band peak at 1,580 cm-1 are shown.
During this phase, photoluminescence band peak position and photoluminescence band width remained constant.
Additionally, the PL band peak position is almost independent of Cr content.
A new Raman band peak was observed at 2276 cm−1 in PMMA-wrapped nanocomposites.
It can be seen that a strong G band peak at about 1594 cm−1 corresponds to graphitic structure, and a weak D band peak indicates a good quality of SWNTs.
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At the same time, the G-band peak position Pg decreases while the sp3 fraction increases.
The doping behavior was further verified by Raman spectroscopy G-band peak downshifts.
Figure 3a shows the Raman spectrum of the graphene film, which contains two major scattering peaks: a 2D-band peak at 2,690 cm−1 and a G-band peak at 1,590 cm−1.
In addition, the roughness values increased and Raman G-band peak position shifted to higher wave numbers.
The examination on G-band peak positions and the I2D/IG ratios for monolayer graphene flake covering on different substrates can provide information of substrate effect.
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