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As such, each averaged spectrum consisted of data from approximately 40 FFT segments representing four breaths.
It is found that the patterns of the averaged spectrum obtained in different other sessions exhibit quite similar nature.
Provided that the respective elevation angles are within ±1.0° of the average elevation angle and the tropospheric opacities are within ±0.05 of the average tropospheric opacity, the corresponding spectra are employed for calculating the hourly averaged spectrum.
A linear pre-edge background function was subtracted from the averaged spectrum, and normalization was performed at an energy value above the absorption edge (11,915 eV), as described by Bhandari et al. [50].
In order to select the data that were not affected by thick cloud, we set the following condition: N ave has to be equal to N total, where N ave is the number of spectra employed for calculating the hourly averaged spectrum based on the criteria described in the previous section and N total is the total number of spectra measured within 1 h.
For reliable and reproducible SERS measurements, a mapping method was employed and an averaged spectrum was obtained by averaging 25 spectra splitted from a mapping result with a scan area of 2 × 2 mm2, a step size of 0.5 × 0.5 mm2 (X × Y).
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The characteristics gas temperature of the plasma filament is estimated from the emission averaged spectra.
d Raw averaged spectra for 5 of the points (images courtesy of Historic Royal Palaces).
The Mn↑ and Mn↓ averaged spectra were obtained only from the affine-corrected data.
The middle panels show the averaged spectra for the hourly intervals corresponding to the upper panel.
The corrected, averaged spectra were smoothed using the 'means-movement' algorithm with a convolution width of 25 using the Jasco spectra analysis program.
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