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To investigate further the effect of pH, a cationic polymer was formed that contained a monovinyl amine monomer and a novel diamine crosslinking agent synthesized in our laboratory.
The membrane prepared using n-hexane had a thick and moderately dense PA layer, due to the limited amine monomer diffusion, accounting for its relatively low performance.
It was also observed that pendant methyl groups had a strong detrimental effect on barrier properties and that using an excess of amine monomer significantly improved the barrier performance.
Two kinds of new electroactive polyamides were synthesized from a novel diphenylamine-fluorene skeleton bis ether amine) monomer "N,N-bis((4-aminophenoxy)phenyl)-2-amino-9,9-dimethylfluorene" 4-aminophenoxy phenyl -2-amino-9,9-dimethylfluorene, respectively.
A novel amine monomer 2,2′-dimethylbenzidine hydrochloride (m-tolidine-H) was reacted with an acyl chloride monomer trimesoyl chloride (TMC) on the surface of a modified polyacrylonitrile (mPAN) membrane.
A new type of linear copolymers, poly ortho ester amino alcohols) (POEAAs), has been synthesized by ring-opening polymerization between diglycidyl ethers and amine monomer with ortho ether bonds.
Similar(49)
The effects of amine monomers, i.e., m-phenylenediamine (MPD) and hyperbranched polyethyleneimine (HPEI), for interfacial polymerization with trimesoyl chloride (TMC) on separation performance are also compared.
This model is expected to predict and explain the diffusion behavior of the epoxy and amine monomers into PSU during the initial time periods.
Scheme 1 Direct arylation polycondensation of N-benzoyl dithieno[3,2-b 2′,3′-d]pyrrole dithieno[3,2-b 2′,3′-d]pyrrole dithieno[3,2-b 2′,3′-d]pyrrolelting in PBDP3HTTPA Scheme 2 Direct arylation of polycondensation of N-benzoyl dithieno[3-hexylthiophenerrole monomers, 3-hexyltrisphene and 1,3,5-tris(4-bromophenyl)benzene monomers, resulting in PBDP3HTTPB.
In this work, a diffusivity model based on free volume theory is presented for the simultaneous diffusion of diglycidyl ether of bisphenol A (DGEBA) epoxy and bis p-aminocyclohexyl) methane (PACM 20) amine monomers into amorphous polysulfone (PSU).
Poly amido amine) (SS-PAA) random and block copolymers having bioreducible disulfide bonds in the main chain and amino groups with distinctly different basicity in the side chain were designed and synthesized by Michael addition polymerization between N, N′-cystaminebisacrylamide (CBA) and two amine monomers, i.e., histamine (HIS) and 3- dimethylamino -1-propylamine (DMPA).
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