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The ozone (O3) decomposition in the pre-heat zone of flames can initiate and accelerate the chain-branching reactions.
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There was a smaller zone of flame shaped haemorrhages at the inferior temporal arcade.
In contrast to previous asymptotic analyses of lean flames and moderately rich flames, where the reaction zone of these flames was presumed to be made up of two layers, for rich flames analyzed here all chemical reaction are presumed to take place in one layer.
The predicted amounts of total aromatic compounds increase at the flame front and remain constant in the postoxidation zone of the flames, attaining the final concentrations of soot, in slightly-sooting conditions.
The present mechanism also well predicted the final values of the NO and N2O mole fractions behind the reaction zone of weak flames but overestimated these mole fractions in the reaction zone of weak flames.
This behavior was associated with the decrease of soot precursors after the main oxidation zone of the flames.
This is in contrast to the reactive diffusive balance that occurs in the reaction zone of premixed flames.
Sensitivity analysis and reaction flux analysis were conducted and the importance of the N2Hx chemistry in the reaction zone of weak flames at low temperatures was identified.
To confirm the existence of N2Hx species in the reaction zone of weak flames, signals from N2H4 were distinguished from measured signals.
The structure of the reaction zone of rich flames is obtained by integrating two second order ordinary differential equations, one giving the consumption of fuel and the other the consumption of oxygen.
For N2O and NO in the reaction zone of weak flames, however, there was discrepancy between measured and computational mole fractions and further improvements of chemical kinetics related to ammonia ignition are still necessary.
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