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As shown in Table 2, IAM and IAA both enhance the reduction of TFA by Synechococcus (1.5-fold increase in the yield of reduction).
Under optimal experimental conditions the total yield of reduction products of CO2 in NaOH aqueous solutions was 406.65 μmol/g-catal.
As shown in Table 2, the yields of the reduction of TFA by the cyanobacterium were increased by the addition of D,L-glyceraldehyde or 5'-AMP (1.5-fold increase in the yield of reduction).
This result can be supported by the lowest deacetylation degree (DD) value (the less free amino groups available for gold ion coordination and reduction, the lower yield of reduction).
These results, which gave a more than 12-fold improvement in the yield of reduction activity per litre of culture, were expected to facilitate use of Acetobacter sp. CCTCC M209061 cells in the production of chiral alcohols as building blocks for many industries.
Additional evidence for the formation of 15 was obtained by running the NaBH4 reaction at a lower pH (5.8 instead of 7.0), which improved the yield of reduction of 2. However, even at low pH, reduction of 2 was not quantitative, perhaps due to the lesser reactivity of the aromatically stabilized cyclic imine toward NaBH4 compared to that of an aldehyde.
Similar(54)
The yields of reduction products were enhanced remarkably by external electrical power.
Addition of DBMIB, an inhibitor of Cyt b 6 -f, resulted in cessation of TFA reduction in the dark, although the chemical yield of ketone reduction without DBMIB was 16% (data not shown).
This interaction induces a higher reductive quenching efficiency of the 3MLCT excited state of the diad with MebpyC2H4Mebpy by the reductant, BNAH, and consequently the quantum yield of CO2 reduction is higher.
The yield of the reduction procedure of 46TiO2 to metallic 46Ti, performed at GSI, was determined by dissolution of the metallic product in conc.
As shown in Figure 2, the highest yield of TFA reduction was obtained in the reaction with 13.4 μmol photons m-2·s-1.
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