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This result seems to be much better than that achieved previously (26% yield) in the polymerization of pure Me2SiCl2.
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A polymer with high molecular weight (Mw = 570 × 103) was obtained in good yield by the polymerization of diphenylamine-containing monomer 1b, whereas the isopropylphenylamine derivative (1c) gave a polymer with relatively low molecular weight (Mw = 2.4 × 103).
The presence of heavy atoms in the xanthene ring increases the triplet quantum yield, but decreases the active radical yield, and then the polymerization rate.
The photoredox pair concentration, the co-initiator structure as well as the light intensity strongly affected the progress of the polymerization, leading, for example, to an increase in the polymerization rate and quantum yield of the process.
There are several factors to consider in polymerization reaction although the combination of PTC and ultrasound is one of the techniques to obtain high yield in polymerization.
Ultrasound creates physical and chemical effects in the polymerization reaction.
Then, SS was immersed in the polymerization solution.
The initial polymerization slop of polymer conversion vs time increases with increasing MBA concentration in the polymerization medium.
The yields were identical when the polymerization was conducted at 60°C and 80°C, but the yield decreased at 40°C, probably by the insufficient reactivity.
Polycarbosilanes were synthesized in good yields by the electroreductive polymerization of the corresponding dichlorocarbosilanes and their analogues.
In their study, the polymerization of wood and bamboo tars with formaldehyde provided resins with yields of 72 and 80%%, respectively [10].
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