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In this study, along with steady shear measurements, oscillatory shear measurements were performed to examine the viscoelastic properties.
The dependence of micelle conformation on temperature was further studied with steady shear rheology.
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With increasing temperature, steady shear viscosity of the Boltorn polymers decreases but the features of shear rate dependence, shear thinning or Newtonian behaviour, remain the same.
However, if the temperature jump is only slight into the hexagonal phase with or without steady shear flow, lamellae are transformed into hexagonally ordered cylinders going through a distinct modulated and perforated lamellar phase stage.
We also observe a power-law increase in G′ and G" at low frequencies in the frequency response measurements and a transition from Newtonian to shear-thinning behaviour, with increasing shear rate, in steady shear measurements.
The overall variation of the oscillatory shear measurement has a close relationship with the results of the steady shear measurement.
(3) A comparison with the results of the steady shear measurement showed that the tendency of the calculated yield stress follows the trend of the storage modulus variation.
Open image in new window Fig. 6 Steady shear viscosity with various amounts of HCl added (0.21 wt% 0.85 wt% HCl) for pH adjustment conducted at 1 wt% DTTM, 20 wt% NaCl solution, and 40 °C.
Steady shear viscosity decreased with increasing shear rate.
When semi-dilute chitosan solutions (<1%) were incubated with p-cresol and tyrosinase, the steady shear viscosity was observed to increase dramatically while oscillatory shear measurements indicated that the chitosan solutions had been converted into a gel.
The rheological measurements of the blends were conducted using a controlled stress rheometer, with dynamic oscillatory shear, as well as steady shear measurements.
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