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The intrinsic fluorescence of HSA was quenched by all the investigated drugs, which was rationalized in terms of a static quenching mechanism.
The experimental results revealed that the UVAS process can reduce scratch loads, effectively inhibit microcrack propagation, and improve the plastic removal proportion, which was rationalized with elastic and residual stress field calculations.
Biological evaluation of these compounds against three typical cancer cell lines established a clear structure-activity relationship at the epoxide region, which was rationalized by comparing the superimposed conformations of different nannocystin analogues and in silico docking analysis.
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Despite their structural modification, all complexes exhibit almost identical emission and excited-state characters, which are rationalized by the quantum-chemical calculations.
An unexpected strain-softening behavior is observed for a silver sample, which is rationalized as a measurement artifact due to the delamination of the film from its substrate.
It is found that the J sc of P3HT/C60-based solar cells increases as the P3HT thickness decreases, which is rationalized in terms of the limited exciton diffusion length in P3HT (~ 10 nm).
Furthermore, the spatio-temporally homogeneous flow facilitates the thermoplastic formability of the Zr-based bulk metallic glass, which is rationalized in terms of free volume theory as well as by finite element simulations.
For each porosity, the joint shear strength is between the tensile strength and the in-plane shear strength of 2D C/SiC, which is rationalized by the rigid body sliding model of 2D C/SiC.
Contrarily, glycerol shows higher power at low concentrations and vice-versa, which is rationalized as a consequence of the poisoning effect due to the limited glycerol catalysis on Pt at high concentration cases.
Atom probe tomography revealed Ti segregation to the columnar grain boundaries and significant Nb intermixing into the bcc Ti layer, which is rationalized as a surface exchange process driven by interfacial thermodynamic considerations.
FAMEs were also found to exhibit different degrees of rotational and translational motions, which were rationalized by chain organization within the clusters, and the degree and type of molecular interactions and temperature effects.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com