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It has been found that hydrolysis of hydrogen peroxide leads to formation of hydroxyl radicals which are responsible for degradation of lignin and production of low molecular weight products.
The formation of higher molecular weight products could explain the lower measured oxalic acid concentrations and slower production rate relative to predictions in the 3000 μM experiments.
In the counterflow flames higher-molecular weight products are slightly over predicted.
It showed the highest conversion and highest composition of low molecular weight products.
Low molecular weight products were also formed, expecially at high current densities.
The oxidation of the lower molecular weight products was also studied to aid the mechanistic interpretation.
Oxybis(benzoylchloride) appears to be a particularly attractive comonomer which allows the synthesis of soluble high molecular weight products.
Analysis of the low molecular weight products by GC-MS showed that microorganisms rapidly assimilated lactic acid and lactoyl lactic acid from the films.
There are, however, exceptions, such as heterogeneous polymerization reactions in which desorption of high molecular weight products can influence the overall reaction rate.
Polymerization at −30 °C was also carried out but only very small amounts of the low molecular weight products were produced.
In HZSM-5 with its relatively narrow pores, all reactions are absent which lead to higher molecular weight products (e.g., dimethylnaphthalenes, coke).
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CEO of Professional Science Editing for Scientists @ prosciediting.com