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These LCB-PSs are also extraordinarily more stretchable during startup uniaxial extension, with the maximum engineering stress emerging at stretching ratio λmax≈4√Mbb/Me, where Mbb is the molecular weight of backbone and Me is the molecular weight between entanglements.
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The effects of SNs content, molecular weight of polymer backbone, and temperature on hydrogels properties are studied, and the results indicate that the physical hydrogel network integrity is depended on the SNs and HAMDs concentration.
Specifically, altering the number of lactide repeat units per crosslinking side chain, percent substitution, molecular weight of PVA backbone, and macromer solution concentration, the rate of mass loss from these degradable networks is controlled.
The simulation results indicate that, as the molecular weight of the backbone polymer is usually much larger than that of the side chain polymer, the polydispersity of the resulting comb polymers is mainly determined by the polydispersity of the backbone at the end of the reaction.
The detection limit depends on the solution properties and the molecular weight of the backbone and branches, but it is expected to be far lower than any other method.
Before crosslinking, the photoisomerization rate is considerably low and totally independent on molecular weights of the backbone whereas, after crosslinking, the rate is dramatically enhanced and highly dependent on the molecular weights.
These values were not dependent on the overall structure or molecular weight of the polymer backbone and were nearly identical to those determined for several lower molecular weight model compounds.
[1, 12, 19, 20, 21] The Meijer group showed that the molecular weight and backbone rigidity of the parent polymer does not significantly influence the SCNP fabrication induced by supramolecular interactions.
"I hope the broadcasters develop a bit of backbone on this because they shouldn't be bullied by the Conservatives throwing their weight around," he said.
"A lot of backbone.
He's got a lot of backbone.
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Justyna Jupowicz-Kozak
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