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The block copolymerization proceeded to intermediate conversions with narrow polydispersities, however at higher conversions some molecular weight broadening was observed and this was attributed to radical-radical termination reactions.
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Additionally, the distribution of molecular weight was broadened from 3.8 to 4.8 (Table 1, run 2).
During ripening, the molecular weight distribution broadened and remained comparable between the mature and ripe stage in both cultivars.
In the cases of lower molecular weight, significant broadening of the stress distribution was observed under elevated stress, and the fracture behaviour was plastic.
Triple-detection gel permeation chromatography (GPC) measurements confirmed the significant enhancement of polymer average molecular weight and broadening in molecular weight distribution with an increase of diacrylate feed concentration as a result of intermolecular cross-linking.
Although living polymerization allows for control over polymer architecture, the production of low molecular weight polymers with low polydispersities via living polymerization systems is challenged by the use of large amounts of catalysts and broadening in molecular weight distribution.
An unexpected trend identified here is that the PMMA molecular weight distribution initially broadens and subsequently narrows with increasing milling time.
The proportions of single chains and termination products were observed to increase with the degree of polymerization of the macromolecular MADIX agents broadening the molecular weight distribution.
Sidelobe reductions of 12 dB and greater can be achieved by this method; moreover, mainlobe energy is preserved well, which is contrast to obvious mainlobe broadening after amplitude weighting.
The Weigh Down Workshop, which is based in Franklin, Tennessee, is now a multimillion-dollar business, and Shamblin has taken the controversial step of broadening her message beyond her weight-loss base.
However, the use of online viscometry in SEC in conjunction with a universal calibration curve leads to the determination of the number-average molecular weight, as demonstrated by a complete derivation that takes band broadening into account [ 75].
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