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The analysis of rheological data reveals a Maxwell fluid behavior for the weakly segregated block copolymers, whereas for the strongly segregated block copolymers a pronounced elastic behavior at low frequencies of small amplitude shear oscillations was observed.
The results suggest that the PCL crystallization kinetic is only slightly disturbed by the segregation strength for weakly segregated systems while the block copolymer sequence shows a strong impact on the overall crystallization kinetics, and particularly on the nucleation step due to topological constraints.
We discuss the kinetics of order order and order disorder transitions in weakly segregated diblock copolymers.
Diblock copolymers in the composition range 37 57% PS show lamellar structures and a partial miscibility due to their weakly segregated phases.
The crystallization and melting behaviors of weakly segregated diblock copolymer (MPEG-b-PLLA) have been investigated by differential scanning calorimetry (DSC), wide-angle X-ray diffraction (WAXD), and small-angle X-ray scattering (SAXS).
As compared with the phase diagram of the weakly segregated diblock copolymers, the phase diagram of the hybrids has two features: the boundaries of the LAM and HEX structures shifts to lower fPEO/salt and body-centered cubic spherical (BCC) structure is not observed for the samples studied.
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In contrast, monovalent lipids such as phosphatidylserine only weakly segregate, and the diffusions of protein and lipid remain largely uncorrelated.
An important prediction of our model is that PIP2 lipids will be able to diffuse in concert with the retarded adsorbed proteins, while lipids such as phosphatidylserine (PS) will only weakly segregate and, in this case, both protein and lipid diffusion will be largely uncorrelated.
Furthermore, in chimeric embryoid bodies composed of N-cadherin and E-cadherin null ES cells, the two weakly interacting cell types segregated but did not envelop one another.
The high protein diversity of O. edulis is therefore partly due to a high load of segregating, weakly selected mutations.
However, as much as 33% of nonsynonymous mutations are sufficiently weakly selected to segregate at low frequency in the polymorphism, which is much greater than usually reported.
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