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The edge decoration observed in Figure 5f is due to the attachment of non-charged or weakly charged nanoparticles that are attracted via polarization effects to the places exhibiting the highest electrostatic field gradient.
Chen, W. & Tong, P. Short-time self-diffusion of weakly charged silica spheres at aqueous interfaces.
A theoretical interpretation used was based on a thermodynamic approach developed for weakly charged gels.
The hybrid approach presented here might enable preparation of mechanically strong nanocomposite hydrogels consisting of strongly or weakly charged polymer chains of different architecture.
These properties are partly attributed to the presence of surface charges, which are due to the biological nature and the presence of weakly charged extra-cellular polymeric substances.
However, the influence of charged groups on structural evolution and dehydration dynamics of weakly charged PNIPAM during phase transition still lacks systematic investigation.
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At the weakly negatively charged Bi(1 1 1) electrode surface there are only physically adsorbed camphor molecules forming the compact adsorption layer.
Then a weakly (anionically) charged Con A should contribute to increase osmotic pressure of the gel, which would help the gel to swell rather than shrink (Figures 3 and 4).
The surface is hydrophilic and weakly negatively charged (< -0.08 C/m) [53] under physiological conditions.
Therefore, differences in the rate of charge-dependent adsorptive endocytosis between cancer cells and normal endothelium is a plausible explanation for the differential uptake of weakly positively charged AuNP3s in cancer cells.
The differential heating rates of weakly positively charged AuNP3s were then compared to highly negatively charged citrate-capped AuNPs (having diameters 5 and 10 nm) at a similar concentration of particles.
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