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For LW bellow 3 nm, the reduction of the exciton energy with increasing LW can be attributed to the weakening of quantum confinement effect.
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Dye, J. L. Electrides: early examples of quantum confinement.
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Malgras, V. et al. Observation of quantum confinement in monodisperse methylammonium lead halide perovskite nanocrystals embedded in mesoporous silica.
Enhancement in electrical resistivity is observed as a result of quantum confinement.
We also discuss the effects of quantum confinement, spatial confinement, and surface localization of excitons on room-temperature luminescence processes in silicon nanostructures.
For quantum dots smaller than 100 nanometers, the peaks become strongly nonperiodic, indicating a major contribution of quantum confinement.
It takes the advantage of quantum confinement effects in silicon.
I vividly remember the explanation from the teleconference it's a consequence of quantum confinement.
The low confinement energy (≈30 meV) is due to the relatively large, but still capable of quantum confinement, thickness.
Higher quantum confinement is expected in sample B as compared to sample A. The possibility of quantum confinement effect in these Si NSs is investigated by Raman experiments.
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