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The higher the complex redox properties and ion exchange processes, the higher is the polarizability of the ion, the smaller is the value of N/R H (N is the number of water of hydration and RH is the hydrated radius] and greater the affinity between the ions and functional groups [37].
Substances that spontaneously absorb water from the air to form hydrates are known as hygroscopic or deliquescent, whereas hydrates that lose so-called water of hydration or water of crystallization to form the unhydrated (anhydrous) substances are known as efflorescent.
Alum, any of a group of hydrated double salts, usually consisting of aluminum sulfate, water of hydration, and the sulfate of another element.
Suitable bauxites contain 50 to 60 percent alumina, up to 25 percent iron oxide, not more than 5 percent silica, and 10 to 30 percent water of hydration.
The water of hydration is essential to the structure of protein crystals; when they are completely dehydrated, the crystalline structure disintegrates.
CuSO4∙5H2O is actually [Cu(H2O 4]SO4∙4H2O; four molecules of water of hydration are coordinated to the copper ion, whereas the fifth water molecule is linked to the sulfate ion, presumably by hydrogen bonding.
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Sulfonic acid (-SO3H) has a high water-of-hydration, absorbing up to 13 molecules of H2O for every sulfonic acid group in the polymer.
Unlike micro-porous membrane permeation, which transfers water through a relatively slow diffusion process, Nafion™ removes water by absorption as water-of-hydration, a first order kinetic reaction that equilibrates within milliseconds.
The term water activity is widely used to define the availability of water for hydration of materials.
Hydrated SPEEK-[M] (M: Cu2+, Ni2+, Cd2+, Pb2+, Sr2+ or Ba2+) exhibits SPEEK-[H] C3V bands because cation waters of hydration preclude binding to the hydrated exchange site.
Their positions appear to agree reasonably well with the distributions of waters of hydration found in 38 x-ray and 1 neutron high-resolution structures of this protein.
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