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XRD, EDS, FE-SEM, diffuse reflectance (DRS) and photocurrent vs potential curves had been used for semiconductor characterization.
Log (steady-state current) vs potential data show that at all temperatures silver undergoes an active-to-passive transition.
The photocurrent vs potential characateristics for three different electrolyte semiconductor junctions, representative of those generally found in semiconductor photoelectrochemistry, are analyzed in detail using parameters which define both the semiconductor and the electrolyte.
Theoretical stationary curves of current vs potential that are mathematical expressions of an electron-transfer reaction, O1 w)+R2(non) ⇌ R1 w)+O2(non), proceeding at the interface of two immiscible phases between the redox couple O1/R1 in the aqueous phase (w) and the redox couple O2/R2 in the non-aqueous phase (non) has been derived.
Procedures for the determination of the diffusion coefficients of the reactants in the corresponding phase and for the evaluation of thermodynamic and kinetic parameters of the electron-transfer reaction from the curve of mean current vs potential of this electron-transfer at the electrolyte dropping electrode have been suggested.
Phase plots (ΔV/Δt vs potential; right) illustrate differences on spiking pattern for the same discharge (Daw et al., 2007 ).
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When applied with 0.9 vs SCE/V potential, the pitting propagation sites corresponded to the high oxygen consumption region.
The number of exchanged electrons was close to 2.7 for both catalysts, and the % H2O2 electro-generated above 60% in the −0.2 to −0.7 V (vs SCE) potential range.
In a boys-vs-potential-damage-to-some-ethereal-notion-of-my-future-self decision making process, boys always won.
The formal electrode potential (vs SCE) was ∼0.37 V.
These models are used for virtual screening (VS) to identify potential new actives or for generating ligand alignments for subsequent QSAR simulations.
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