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The phrase 'volatile character' is correct and usable in written English.
You could use it to describe a person whose behavior or emotions can suddenly change in an unpredictable manner. For example, "John's volatile character made it impossible to predict how he would react in any given situation."
Exact(30)
We know Steele is a volatile character.
I saw no sign of a volatile character — he was confident of his prospects.
A volatile character, some say he was unlucky not to have played more.
Rumours that she inspired the volatile character of Juliette Barnes (pictured, right) in "Nashville" have been vigorously denied.
He has also been a somewhat volatile character in the past, and has passed through a number of yards.
Since the mid-20th century his violent exploits and volatile character have enhanced his popular appeal as a perceived outsider and rebel against convention.
Similar(30)
They can just criticize the volatility, but there will be some pretty volatile characters on that stage tonight, and elsewhere in Iowa.
Much of that is because Gonzalez has emerged as one of the most divisive and volatile characters in the conference.
Both players are feisty, provocative, volatile characters, as their records for their clubs, and their national teams, have long shown.
Ms. Wright is a dab hand at building suspense from the psychological state of her volatile characters.
Woodson has indisputably been a net positive for the Knicks, corralling a locker room of volatile characters and disparate talents and presiding over the franchise's best season in more than a decade.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com