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Finally, the photovoltaic performances of these polymers have been assessed by photocurrent transient measurements carried out under visible illumination.
3DOM Au/TiO2 photocatalysts exhibit high catalytic activity for the photocatalytic reduction of CO2 with H2O to CH4 under visible illumination.
Visible illumination resulted in the formation of the plate-like structures, whereas UV illumination resulted in fragmentation of the assembling structures.
Adsorbed catecholate behaves as a charge transfer complex, which can be excited with visible light, as evidenced by Raman Spectroscopy, making possible photocatalytic activity under visible illumination.
Electrochemical impedance and action spectra suggest significant photon to current conversion efficiencies of the material under UV-vis as well as for visible illumination.
In combination with the strong absorption of visible light corresponding to the surface plasmon resonances (SPRs), these composite particles exhibit enhanced photocatalytic performance under visible illumination in comparison to the Au or Ag nanoparticles without the hierarchical morphologies.
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The CV of Au/GCE in 0.1 M PBS (pH 7.0) solution containing 1.0 mM UA without (1) and with (3) visible light illumination; visible light illumination starts from the spot where the arrow is pointing (2).
In the absence of visible light illumination (1) and at various levels of illumination (2 to 5).
The influence of visible light illumination was studied by adding the visible light illumination at a certain time in the process of a successive cyclic voltammetry.
The electroanalytical results of as prepared Au/GCE under visible light illumination exhibited obvious superiority compared with non-visible light illumination due to the surface plasma resonance (SPR).
Besides, the oxidation peak potential of Au/GCE under visible light illumination is approximately 6 mV negative than that without visible light illumination.
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