Sentence examples for vinyl moiety from inspiring English sources

The solution-processable polymer can be cast into a film, masked and patterned by UV-initiated free radical polymerization of the vinyl moiety.

Reactivity ratios and Alfrey-Price parameters suggest that the biphenylyloxy unit successfully insulates the vinyl moiety from the σ-electron withdrawing effect of the cyclophosphazene ring.

Here we describe incorporation of a vinyl moiety into a peptido sulfonyl fluoride backbone, which should lead to a combined attack of the proteasome active site threonine on the double bond and the sulfonyl fluoride.

The internal rotation barrier of the vinyl moiety has been also calculated and a conformational analysis has been afforded in detail through different energy factorization schemes, i.e., the total kinetic and potential scheme and that provided by the NBO theory.

Sensitivity and rate of production analyses were performed and showed that, at the conditions studied herein for the flame speed investigation, the main fuel consumption pathways include the reaction of the fuel with H atoms to form phenyl radical and ethylene or benzene and vinyl radical, with O to form benzyl radical + HCO, and the H-abstraction reactions on both the vinyl moiety and the ring.

This is important for biocatalytic applications and indicates that the vinyl moiety of phenyl vinyl sulfide is bound in the StyA active sites remote from the flavin hydroperoxide.

To enable such control, noncanonical amino acids bearing vinyl moieties via allyloxycarbonyl (alloc) groups were incorporated adjacent to MMP-sensitive peptide sequences to act as weak competitive cross-linking sites with very low free radical propagation during photopolymerization.

At a fixed modification time of 10 min and employing pristine polymers prepared from 1, 4, and 16 wt % AIBN, a greater amount of vinyl moieties that reacted with thio-glycolic acid is detected for pristine materials prepared at the lower initiator concentrations.

In the other series, the electrophilic vinyl sulfonate moiety was introduced as a novel class of HCV NS3/4A protease inhibitors.

Herein, we demonstrate that some simple molecules containing a vinyl sulfone moiety are not thiol-specific alkylants since they react with some albumin nucleophiles including side chains of Cys34 and His146.

Different types of novel xanthates containing a vinyl ether moiety, S-benzyl O-2- vinyloxy)ethyl O-2- vinyloxyate (Xanthate 1) and S-1-(ethO-2- vinyloxythyl O-2-(vinyloxy)ethyl carbonodithioate (Xanthate 2) were synthesized.