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Finally, grate the garlic straight into the pot and give it a vigorous stir.
Place the tub in the freezer for 30 minutes, then give the mixture a vigorous stir with a fork or whisk to break up any ice crystals.
Subsequently, the metal nitrates/DMF solution (4 mL) was added slowly to the PVP/ethanol solution (50 mL) under vigorous stir at 27 °C for 5 h to obtain a well-dissolved solution.
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m-SiO2 nanospheres were prepared as follows: surfactant hexadecyl trimethyl ammonium bromide (CTAB) (300 mg) was added to a mixture of ethanol (EtOH) (60 ml), distilled water (80 ml) and ammonia (25 wt %, 1,1 mL), then sonicated and subsequent vigorous stirred.
A few vigorous stirs should do the trick.
A 0.3 ml volume of freshly prepared, ice-cold, 10 mM NaBH4 was then added under vigorous stirring and stirred for another 2 mins.
Tetraethyl orthosilicate (TEOS, 7.75 mL, 35 mmol) was added under vigorous stirring and the dispersion was stirred for 2.5 h.
Colloidal silica (Ludox HS-40, Dupont, Wilmington, DE, USA) was then added under vigorous stirring, and the gel was stirred at room temperature for 5 min.
A solution of tetraethylammonium bromide (5.3 g 0.025 mol) in 25 ml of deionized water was added dropwise via the dropping funnel with vigorous stirring over at least 1 h, and the solution was stirred overnight [2].
Under vigorous stirring, ammonium hydroxide (6.25 mL) was added, and the suspension was continuously stirred in air for 10 min.
After vigorous stirring for 0.5 h, 2.5 mmol malonic acid was added to the solution, and then the reaction system was vigorously stirred for 24 h in 4 °C.
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