Sulfhydryl groups of vicinal or closely spaced cysteines are typical high-affinity targets for trivalent arsenicals in protein structures (Altamirano et al. 1989; Carlson et al. 1978; Chakraborti et al. 1992; Delnomdedieu et al. 1993; Li et al. 2001; Lopez et al. 1990).
We have developed a synthetic approach to merging a naturally occurring 1-azaadamantane core with a vicinal amino alcohol moiety that is also common in natural product chemical space.
This means that, for fixed annealing conditions, a higher growth rate is expected on vicinal, i.e., off-axis, SiC surfaces than on on-axis ones, because the spacing between terraces kinks is reduced.
In Si 553 -Au and related vicinal Si 553 -Aurfands, this anisotrelatedises naturally at the step edge.
Visinoiu, A. et al. Initial growth stages of epitaxial BaTiO3 films on vicinal SrTiO3 (001) substrate surfaces.
Fusano, A., Sumino, S., Fukuyama, T. & Ryu, I. Vicinal C-functionalization of alkenes.
Altmann, K. N. et al. Electronic structure of atomic chains on vicinal Si(111 -Au.
Surfers are like farmers or hunters in their rapt absorption in nature's vicinal habits and vagaries.
Mysliveček, J. et al. On the microscopic origin of the kinetic step bunching instability on vicinal Si 001).
For example, step edges on vicinal Si(111) can be atomically smooth for distances as great as 20,000 lattice sites5.
Several other Au-stabilized vicinal (111) surfaces contain structural motifs in common with Si 553 -Au and Si 553 -Au8.
