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According to vibrational spectroscopy, the enhanced HOOP vibration bands in the K intermediate mainly come from the H D exchangeable groups, implicating that the chromophore is distorted at the RSB region.
Table 1 showed the characteristic vibration bands of different locations.
The main vibration bands in the spectra have been highlighted.
Si O Si asymmetric stretching vibration bands occurred at 1075 cm−1 [28].
The observed vibration bands at 988 and 240 cm−1 are the most intense.
In addition, 1048 and 881 cm−1 are related to –NH2 vibration bands.
Spectral bands specific for pigments - white lead (vibration bands of 1399, 1038 and 838 cm—1) and chalk (vibration bands of 1417 and 876 cm—1) are clearly recognized, too [7].
The asymmetric and symmetric stretching H-O-H vibration bands are observed between 3,600 and 3,200 cm-1, while the bending H-O-H vibration bands are observed between 1,630 and 1,600 cm-1[36, 37].
The peaks around 1,500 1,652 cm−1 suggest that aromatic ring bands and double bond (C=C) vibrations overlap with C=O stretching vibration bands and OH bending vibration bands.
Finally, the resultant vibration bands at lower-frequencies areas recommended the formation of codoped Mn2O3-ZnO NPs.
The IR spectra of 1 show broad vibration bands of ν(NH2+) in the region 2800-2200 cm-1.
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