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Polymerizations of 4-propionyloxybenzoic acid, 4-hexanoyloxybenzoic acid, 4-octanoyloxybenzoic acid and 4-decanoyloxybenzoic acid in liquid paraffin at 320 °C yielded needle-like or pillar-like POB crystals via crystallization of oligomers.
Thin nanotubes (diameter <20 nm) are formed via crystallization of the disordered carbon with the preferred formation of the (0 0 2) basal planes.
As a relatively new approach, the possibility to enhance polymer/filler interfacial interaction via crystallization of polymer on the surface of fillers, i.e., interfacial crystallization, is summarized and discussed in this paper.
Then, the particles grew rapidly into the broom shape via crystallization of nanoparticles coupled with a simultaneous multiscale assembly.
The unique structure of carbohydrate-binding domains might contribute to the binding preference of AAL-2 to terminal β-GlcNAc-linked oligosaccharides; our future studies will focus on the analysis of the carbohydrate lectin interactions via crystallization of the AAL-2 and GlcNAc complex.
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A well designed S-1/Pd/ZSM-5 core-shell structure was prepared via secondary crystallization of S-1 layer on the Pd/ZSM-5 core.
B39T18 and B41T44 were selected, and crystalline nanowires were formed for B39T18 cast from non-selective solvent via the crystallization of PPP block overwhelming P3HT block.
Here, we demonstrate the fabrication of a microporous membrane and its surface modification via solvent crystallization of a polymer solution under a temperature gradient, similar to the natural process to form permafrost and the subsequent polygonal ground pattern produced during glacier formation.
For instance, Hu et al. [ 9, 10] demonstrated that unaged PLA/PEG blends, containing 30 wt% of PEG with M of 8,000 g mol−1, were low modulus elastomeric-like materials with Tg at 7 °C, but they aged via either crystallization of PEG and PLA or phase separation and, as a result, their Tg increased and behavior changed over a relatively short time to higher modulus thermoplastic-like.
Because of the comparatively large sensible heat and latent heat contribution to the crust necessary to produce silicic magma compositions (>65 wt% SiO2) via crystallization, the generation of silicic volcanism is the dominant signal in our calculations of the Quaternary magmatic heat budget (Fig. 4b).
This paper discusses a novel low temperature process capable of producing super-azeotropic hydrochloric acid via the reactive crystallization of calcium sulfate α-hemihydrate, a valuable by-product, in a continuous stirred-tank reactor (CSTR).
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