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If the transition metal cation bridges two different macromolecules in the glassy state via coordination crosslinks, then 5-coordinate complexes with one surviving metal polymer bond above Tg represent reasonable geometries in the molten state.
Such PAA coating provides sufficient bonding sites to fix TiO2 via coordination, because the abundant hydroxyl groups of PAA layer offer active coordinate sites to fix TiO2 at higher dispersion.
Fujita, M. et al. Molecular paneling via coordination.
Furthermore, we anticipated that a pendant chelating group could facilitate the capture of the alkyl radical by the nickel species, while also controlling chemoselectivity and regioselectivity via coordination.
The use of metal complexes allows formation of targeted protein-bound adducts that show binding via coordination or noncovalent interactions.
Moreover, the growth mechanism of nitrogen and sulfur co-doped bio-carbon materials from chicken feather via coordination reaction and biomineralization process is investigated.
Similar(25)
The construction of a new family of multiferrocenes end-capped metallodendrimers H1 4 with various generations via coordination-driven self-assembly was described.
We designed and constructed a new family of 60° dendritic dipyridyl donors, from which two novel triangular metallodendrimers were successfully prepared via coordination-driven self-assembly.
Two novel, supramolecular, multiferrocenyl rhomboids 5 and 6 have been successfully constructed from newly designed 60° ferrocenyl donor precursor 1 via coordination-driven self-assembly.
A new family of 120° polysulfurated dipyridine donors have been successfully designed and synthesized, from which a series of novel rhomboidal and hexagonal supramolecular polysulfurated metallodendrimers were prepared via coordination-driven self-assembly.
The solvation model of cations forming cross-links via coordinations to ether oxygens of adjacent chains is favoured.
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