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Our results are in good agreement with experimental values for the bulk band-gaps.
In all three systems, calculated redox potentials approach values for the bulk solution for droplet radii of about 10 nm.
Good agreement is observed only after conducting a parametric study to identify more appropriate values for the bulk acoustic properties.
In addition, the impedance analyses provided values for the bulk polymer parameters including diffusion coefficient (D), equilibrium capacitance (C0) and diffusion resistance (R0).
The well-defined values for the bulk phase phonon MFP can be extracted [25] from experimental values of the bulk lattice thermal conductivity [26, 27] and phonon dispersions.
The optical spectrum indicated two direct bandgaps at 2.3 and 3.2 eV which are blueshifted relative to reported values for the bulk sample.
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The D values for the bulk-mudrock samples were slightly lower than those of the washed samples, while the kerogen samples showed lowest values.
For all the prepared samples, the values of m are found to be close to the value for the bulk.
The highest value for the bulk modulus ratio found in this study is 2.2 for a sea water-exposed clay; and (4) two empirical equations for estimating parameter b are established.
As described in Section 2.3, the procedure for obtaining fLCI measurements assumes a constant RI value for the cell nuclei, and a different constant value for the bulk tissue; however, it is known that the RI can vary depending on tissue type and tissue health.
This is due to the well-known deterioration of the convergence behavior of the penalty method for large values of the bulk modulus.
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