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We thus have developed a practical method for the synthesis of polyglycerols containing low amounts of Ca. Glycerol is a simple yet functionalized, renewable platform chemical that can be used as a building block for a large variety of commodity chemicals.[ 1– 5] One such valorization route is the direct catalytic etherification of glycerol to polyglycerols.
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The objective of the research work was to investigate potential valorization routes for these biomass agro-residues in the context of a biorefinery, focusing on lignin extraction.
Thus we do not further discuss this route for valorization of crude glycerol in this work.
For temperatures below 200 °C, both glycerol and CO2 were converted, suggesting a potential route for glycerol valorization and CO2 sequestration, with the consequent production of oxirane, alcohols, ketones and carboxylic acids.
The gasification of impregnated olive mill wastewater/exhausted olive mill solid waste pellets was selected as a promising route for their valorization and the reduction of the pollution impacts of olive mill wastewater.
The route of biotechnological valorization of glycerol can follow three different pathways.
The most studied route of biotechnological valorization of glycerol is related to its conversion to 1,3-propanediol (1,3-PDO).
With the possible advances identified (reduced water or acid/base consumption, improved conversion in pretreatment, and lignin valorization), the MESP could be reduced to around $3/gal $3.22 in the WW route and $2.8 in the OP route).
Increasing interest in biomass valorization has triggered a worldwide search for new catalytic routes to transform biomass-based derivatives in transportation fuels and valuable chemicals.
This study investigates the synthesis, characterization and the catalytic application of bimetallic Cu-Ni catalysts supported on pure MCM-41 and Ti incorporated MCM-41 porous materials for the valorization of a lignin model compound (i.e. guaiacol) into the transportation fuels via hydrodeoxygenation route (HDO).
Sheldon, R. A. Green chemistry, catalysis and valorization of waste biomass.
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