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The effects of reaction conditions such as temperature, time-on-stream, O2 concentration, CO concentration and space velocity on CO conversion and selectivity were also investigated in a microreactor flow system using the optimum catalyst obtained.
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The rest of the experiments was carried out using the optimum concentration of the catalyst, which is 100 mg/L.
Using the VREA, the optimum catalyst loading was estimated to be 0.4 g/L.
Specifically on catalyst design, ANN was used to determine the optimum catalyst conditions for obtaining maximum hydrogen production performance of a Ni/Al2O3 catalyst for the production of hydrogen by the catalytic reforming of crude ethanol.
The composition of the optimum catalyst was Cu/Zn/Al/Sc/B/Zr=43/17/23/11/0/6 prepared using 2.2 times the equivalent of oxalic acid and calcined at 605 K.
The obtained optimum model was used as fitness function for hybrid genetic algorithm to find the optimum catalyst.
The optimum theoretical ratio of MnO2 to the CNT used in synthesis was 60% (w/wcarbon) but the TGA analysis confirmed that the exact MnO2/CNT ratio in the optimum catalyst was 41% (w/wtotal).
The optimum catalyst loading was observed at 2.0 g/L.
So, the catalyst concentration of 3 wt% was noted as the optimum catalyst concentration for transesterification (Fig. 9).
The optimum catalyst concentration is 0.025 mol/L Co(NO3 2.
Therefore, the optimum catalyst loadings was found to be 18 wt% in this system.
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