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The formation of H2O2 during the ORR was reduced by at least three fold when using the bifunctional catalyst as compared to the non-modified perovskite.
The results obtained at TR = 513 K, PR = 3.0 MPa and GHSV = 9000 NL gcat−1 h−1 show a superior DME productivity (4.4 mmol kgZCZ−1 s−1) using the bifunctional catalyst prepared by physical mixing.
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Furthermore, the formation of HMB was more pronounced over the bifunctional catalyst by using H-beta as an acidic component.
The stability of the bifunctional catalyst, Cu ZnO ZrO2/Al H-mordenite, was investigated for direCu ZnO ZrO2/Al H-mordenitedrogenation.
In order to assess the stability of the bifunctional catalyst, several accelerated degradation tests were performed.
The efficacy of the bifunctional catalyst system for combined hydrogenation/esterification was demonstrated.
The best results were obtained with the bifunctional catalyst prepared from 3,5-di trifluoromethyl -aniline under solvent-free conditions.
In this case, the biopolymers played double roles of the support and also active part of the bifunctional catalyst.
In our previous study, we showed that the appropriate molar ratio of elements in the bifunctional catalyst (hydrogenation to dehydration) was 2 1 (Khandan et al. 2009).
Both catalytic dehydration reactions and a host of other processes can be facilitated by nanoporous catalysts that contain one or more types of spatially well-isolated active centres epitomized by the bifunctional catalyst shown in Fig. 13.
The complex interactions of the bifunctional catalyst composition, feed composition and multi-stage configuration play a central role in the extent of the synergy.
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