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IR studies were carried out using a Shimadzu Model Fourier transform infrared (FTIR) Prestige-21 spectrophotometer.
All FTIR spectra was obtained using a Shimadzu Model IRPrestige-21 spectrophotometer.
Fourier transform infrared (FTIR) spectra (KBr disc approach) were carried out using a Shimadzu Model IRPrestige-21 spectrophotometer.
Analyses of organic and inorganic carbon were performed on unpreserved samples using a Shimadzu model TOC-V CPH/CPN using ASTM Method D-7573-09.
Analyses of organic and inorganic carbon were performed on unacidified samples using a Shimadzu model TOC-V CPH/CPN using ASTM Method D-7573-09.
Dissolved organic carbon (DOC) was determined using a Shimadzu model TOC5000© high temperature combustion carbon analyzer and analysed using the high temperature catalytic oxidation method (Sharp et al., 2002).
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The crystalline phases of synthesized catalysts were analyzed by powder X-ray diffraction analysis using a Shimadzu diffractometer model XRD 6000 with employing Cu-Kα radiation to generate diffraction patterns from powder crystalline samples at ambient temperature.
The structure of the NiFe2O4 nanoparticles was characterized by the X-ray diffraction (XRD) technique using a Shimadzu diffractometer model XRD 6000 (Nakagyo-ku, Kyoto, Japan) employing Cu Kα (0.154 nm) radiation to generate diffraction patterns from powder crystalline samples at ambient temperature in a 2θ range of 10° to 70°.
Carbon dioxide was measured in the headspace using a Shimadzu GC model GC -17A (Shimadzu Scientific Instruments, Columbia, MD), with a thermal conductivity detector and a 168 mm HaySep 100/120 column.
All assays were performed at 30°C using a Shimadzu spectrophotometer (Model 1700 UV Vis, Japan) equipped with a constant temperature cell holder.
Enzyme activity was continuously recorded up to 90 s, at 412 nm, using a Shimadzu spectrophotometer, model UV-160 A, according to the Ellman method [ 14].
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