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Water samples were analyzed by inductively coupled plasma mass spectrometry (ICP-MS) at the Trace Element Analysis (TEA) Core at Dartmouth using a quadrupole collision cell 7500c Octopole Reaction System (Agilent) and helium as a collision gas to remove polyatomic interferences.
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For structure identification of the metabolites, collision induced dissociation spectra were recorded by selecting the precursor ion using a quadrupole analyzer (transmission window 2 Da) and the product ions were resolved by the TOF analyzer.
It is possible to reduce the kinetic energy of a collimated particulate ion beam through collisions with a buffer gas while radially constraining their motion using a quadrupole guide or trap over a limited mass range.
The analysis of the breakthrough gas was performed using a quadrupole mass spectrometer.
Real-time measurements of CO conversion are done using a quadrupole mass spectrometer.
Hydrogen thermal desorption analysis (TDA) was performed in vacuum at 10−6 Pa using a quadrupole mass spectrometer.
Oxygen consumption and formation of the reaction products were monitored using a quadrupole mass spectrometer (Pfeiffer Vacuum OmniStar 200).
Hydrogen thermal desorption analysis (TDA) was performed under vacuum at 10−6 Pa using a quadrupole mass spectrometer.
Tap water samples were tested at the Trace Element Analysis Core at Dartmouth using inductively coupled plasma mass spectrometry (ICP-MS) with a quadrupole collision cell 7500c Octopole Reaction System ICP mass spectrometer (Agilent) and helium as a collision gas to remove polyatomic interferences, as described previously by Karagas et al. (2001).
The key element of the mass spectrometer is a novel high ion capacity ion trap, combined in tandem configuration with a quadrupole collision cell and a quadrupole mass analyzer (i.e. a TrapqQ configuration).
We used a quadrupole mass spectrometer (Trace-MS; Fisons/Thermoquest, Antwerp, Belgium).
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