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These experiments have been modeled using a kinetic mechanism automatically generated by EXGAS, the system developed in Nancy.
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The pyrolysis and oxidation of diacetylene were modeled using a kinetic reaction mechanism including recent sub-mechanisms for formaldehyde, ketene, acetylene, ethylene, and ethane oxidation.
The pyrolysis and oxidation of acetylene were modeled using a kinetic reaction mechanism, including the most recent mechanism for formaldehyde and ketene oxidations.
The pyrolysis and oxidation of methane were modeled using a kinetic reaction mechanism including the most recent mechanism for formaldehyde, ketene, acetylene, ethylene, and ethane oxidations.
The pyrolysis and oxidation of ethylene were modeled using a kinetic reaction mechanism including the most recent mechanism for formaldehyde, ketene, methane, ethane, and acetylene oxidations.
The reaction was previously studied using soluble tryptophanase, a kinetic mechanism proposed and the catalytic properties of the enzyme described.
The use of a kinetic mechanism to control relative rates, and therefore outcomes, of competing reactions is well-documented in biology.
Numerical solution of the equations of mass, species, and energy conservation are performed using a chemical kinetic mechanism recently developed at the National Institute of Standards and Technology.
Results are reported from three-dimensional direct numerical simulations of nonpremixed hydrogen-oxygen combustion using a reduced kinetic mechanism in low Mach number, decaying, variable density, isotropic turbulence.
The formation and dynamics of premixed cool flames are numerically investigated by using a detailed kinetic mechanism of dimethyl ether mixtures in both freely-propagating and stretched counterflow flames with and without ozone sensitization.
For values of equivalence ratio greater than 1.3, burning velocities obtained from the asymptotic analysis are found to agree reasonably well with those obtained using a chemical-kinetic mechanism made up of elementary reactions.
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