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By using a functional initiator, functionalities such as vinyl, hydroxyl, epoxide, cyano and other groups have been incorporated at one chain end, while the other chain end remains an alkyl halide.
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We demonstrate that a single one-step approach based on dual simultaneous polymerizations is a viable technique for the synthesis of a wide range of block copolymers by combining two dissimilar polymerization systems and using a dual-functional initiator.
Further transfection assay and mutation analysis showed that the core promoter contains a functional initiator.
Interestingly, the presence of a functional initiator sequence can provide resistance against NC2-mediated transcriptional repression [ 35].
Essentially, the organization used a functional structure.
A gel polymer electrolyte (GPE) was successfully prepared by means of an in situ cross-linking reaction of poly 2-vinylpyridine-co-styrene) and oligo(ethylene oxide) with epoly 2-vinylpyridine-co-styrene°C without using a poly 2-vinylpyridine-co-styrene
Emerging reports suggest that temporarily trapping the monomer in a dormant state enables new possibilities in controlled supramolecular chain-growth polymerization using a suitable initiator.
Microwave irradiation was conducted using a Biotage Initiator unit.
Microwave-assisted chemistry was performed using a Biotage initiator microwave synthesiser.
The kinetic behavior of VPA copolymerization with styrene or MMA using a hydrophobic initiator was investigated by reaction calorimetry.
The liquid crystalline block, with a terminus suitable for azo coupling reaction, was obtained by ATRP using a synthesized ATRP initiator with the designed functional group and a side-on liquid crystalline monomer.
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