"urgently ask" is correct and can be used in written English.
It usually refers to asking someone to do something quickly. Example sentence: I urgently asked my friend to help me finish the project on time.
It also needs to — humbly and urgently — ask its allies in Europe, Asia and the region for help.
Climate change is here now, and it's time to urgently ask ourselves: What kind of future do we want to work toward?
Nevertheless, issues of co-morbidity and limited availability of donor nerves urgently ask for a need of bioartificial nerve guides which could either replace or complement autologous nerve grafts.
In response, Mr. Carlisle of the Tobacco Manufacturers Association said, "We would urgently ask the minister to talk to us before framing any legislation so we can help them make sure that what they're proposing is workable".
Herein, we urgently ask the vendors and manufacturers of antibodies to provide the necessary product sheets for all types of antibodies on a regular basis, including quality control documentation for each batch of polyclonal and each catalog number of recombinant or monoclonal antibodies.
Could I do something, I was urgently asked.
Throughout the time he was at Guantánamo, he was urgently asking for lenses. . . .
"What, if not this deep translation, is your ardent aim?" the Ninth Elegy urgently asks.
But other detainees, from Bangladesh, Tunisia and Iraq, were eager to talk and urgently asked for help.
The elderly lady had urgently asked to see the pharmacist, and was clearly distressed.
Even as I was writing this, I found a website full of people urgently asking how to sign up.
