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The effects of the mutation on the first-flash spectrum were similar to those of the S2/S1 spectrum in Figure 2, e.g., slight upshifts of the peaks at 1416, 1398, and 1364 cm 1 to 1418, 1402, and 1366 cm 1, respectively, in the symmetric COO– region and decreases in intensities of the 1588, 1543, and 1523 cm 1 peaks in the asymmetric COO /amide II region.
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Absorption spectra show the well-known upshift of the energy bandgap with decreasing NC size.
Absorption measurements showed an energy upshift of the energy bandgap of the Si NCs with decreasing size.
The upshift of the G band reflects doping with charged impurities.
This p-doping was reflected by the upshift of G band [53].
The significant upshifting of the laser frequency takes place when the laser carries higher intensity (Fig. 7).
In the BNNRs-MB sample, we observed an upshift of the BN stretching vibration related peak at 1394 cm−1.
It is worth noting that the formation of covalent bonds can be evidenced by the upshift of 2D peak from 2,685 to 2,691 cm−1[31].
We also found a progressive downshift (upshift) of both the E12g and A1g Raman active modes with increasing level of applied tensile (compressive) strain.
In general, annealing results in a narrowing and an upshifting of the G-band together with an increase in the ID/IG ratio.
Interestingly, the decrease in I 2D/I G ratio, along with the upshift of 2D and G bands, would indicate a doping effect in the graphene for BDMT/G.
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