Sentence examples for upon coordination of from inspiring English sources

The photochemical properties of the metal porphyrin/phthalocyanine and fullerene moieties are shown to be tuned in a controlled manner upon coordination of metal center.

However, instead of separate (C60 2M molecules, a polymeric chain is formed, which is probably indicative of enhanced reactivity (with respect to ligand-free palladium) of the other fullerene double bonds upon coordination of one bond.

The spectroscopic data provide a coherent picture, which is consistent with a Boltzmann ground-state distribution of several rotamers that are locked into a more flattened geometry upon coordination of Cu(I).

Upon coordination of Cu II), the hinge shut.

As the protein is deprotonated upon coordination of the metal ions, the binding ligand is negatively charged.

In addition, the σ-complex D, which is formed upon coordination of cyanamide to C, was identified by neutral loss experiments.

124 Given the dominance of Lewis acid-Lewis base interactions over other interactions and the resulting loss of their acidity upon coordination to chiral ligands, Lewis acid-catalyzed asymmetric reactions in water using hydrophilic substrates are recognized as highly challenging, even though chiral induction can be achieved in aqueous media.

Dynamic NMR spectroscopy of a Pd II) complex has shown that there is an efficient stereochemical control of the sulfur configuration upon coordination to the palladium.

The fluorescence emission of the GQDs was quenched upon coordination to the respective Pcs.

Upon coordination to a copper catalyst, oxaziridine 23 becomes activated toward substrate-induced homolysis of the N O bond.

Upon coordination to metal centers, the 13C carbene resonance usually shifts highfield, depending on the Lewis acidity of the complex fragment.