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In 5 PHEN is a space demanding ligand upon coordination with the Pb II) ion it forms a seven coordinated holodirected distorted pentagonal bipyramidal complex instead a hemidirected one with less coordination number.
In most of the cases higher activity was exhibited upon coordination with vanadium(IV) metal.
The fluorescence emission of the GQDs was quenched upon coordination to the respective Pcs.
Upon coordination, the IC50 value of the transition-metal compounds is improved compared to the free ligand.
Dynamic NMR spectroscopy of a Pd II) complex has shown that there is an efficient stereochemical control of the sulfur configuration upon coordination to the palladium.
The photochemical properties of the metal porphyrin/phthalocyanine and fullerene moieties are shown to be tuned in a controlled manner upon coordination of metal center.
Similar(33)
AqI shows emission quenching followed by fluorescence turn-on upon coordination-mediated complexation of Hg2+ ions.
In all cases, aluminium toxicity is largely conditioned by aluminium bioavailability, which in turn hinges upon aluminium coordination chemistry in vivo.
The results showed that metal ions did exert great influence upon the coordination modes and the geometrical conformations of ligands and the topological structures of the final products.
The aspartic side chains participate in the cleavage of the DNA strands along the minor groove, resulting in the hydrolysis of specific phosphodiester bonds upon the coordination of three divalent metal ions8.
The frequency of these bands depends upon the coordination mode of the carboxylate ligand.
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