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The phrase "unexpectedly different" is correct and usable in written English.
It can be used to describe something that is surprisingly not the same as what was anticipated or expected. Example: "The results of the experiment were unexpectedly different from our initial hypothesis, leading us to reconsider our approach."
Exact(14)
"We felt so suddenly and unexpectedly different to everyone else.
This experiment demonstrated that microEEG signals do not contain activity at levels that are unexpectedly different in any frequency range from those recorded by the standard device.
However, significant power supply may need to be quickly secured if there are failures in supply or if real-time (actual) demand is unexpectedly different than that predicted day-ahead, e.g., due to weather conditions.
One important finding was that the resistive layer in this area of the lithosphere is unexpectedly different from that detected in the area off the Bonin Trench (Baba et al. 2010), although the lithospheric ages differ little between the two areas.
If the structure-activity correlation for a set of molecules is represented by a 3D plot in which the x, y axes correspond to two principal components and the biological activity is along the z axis, then this landscape may have activity cliffs when compounds with similar structure have unexpectedly different activities.
The demo is unexpectedly different from the versions available at PAX and Firstlook.
Similar(45)
Not unexpectedly, the different −228 and −60 constructs provided slightly different results in terms of basal and induced activity with different regulatory element insertions.
Comparison of spread F occurrence at Indian and Brazilian equatorial locations show, unexpectedly, quite different statistics.
The tendons of high-heels wearers, although unexpectedly no different in length, were about 20% less flexible than the tendons of flat-shoe wearers.
Specifically, repeated tests conducted with the same solid propellant resulted, unexpectedly, in different standing wave structures in the impedance tube when the exhaust configuration was changed.
Egress of OLA129 was observed in all the thirty runs, and unexpectedly, three different egress routes were found for OLA129 (Table 1 & Table 2).
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Since I tried Ludwig back in 2017, I have been constantly using it in both editing and translation. Ever since, I suggest it to my translators at ProSciEditing.

Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com