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The insertion product 24 bearing two ortho-methyl groups undergoes reduction and a radical sp3 C H amination reaction to form 2,3,4,5-tetrahydro-1H-benzo[c]azepine 5066.
Importantly, the nitro group of 2-NO2 undereductionuction before the second-electron reduction of the 4-benzoylpyridinium system.
Under commercially relevant FTS conditions the catalyst undergoes reduction and minimal amounts of cobalt aluminate were found.
The acetoacetyl-S-ACP, for example, undergoes reduction to β-hydroxybutyryl-S-ACP [65]; the reaction is catalyzed by β-ketoacyl-ACP reductase.
These sensors are designed to react with one class of gases whereby the SMO undergoes reduction and oxidation.
Ruthenium tetroxide, RuO4, formed by oxidation of ruthenium VI) in acid, readily undergoes reduction to ruthenate VI),.
After medroxyprogesterone is ingested it undergoes reduction and hydroxylation in the small intestine [ 23, 24].
The posterior portion of the larval metacoel undergoes reduction: its lumen disappears (Fig. 4a, d).
This bulge gradually undergoes reduction and completely disappears by day 9 after the onset of metamorphosis (Fig. 4d).
Romidepsin is a prodrug with disulphide bond which undergoes reduction in cells by cellular reducing activity involving glutathione releasing a zinc-binding thiol.
After FabB and FabF, the lipid intermediate undergoes reduction of the carbonyl group by the NADPH dependant β-ketoacyl-ACP reductase (FabG), producing the intermediate β-ketoacyl-ACP.
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