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Probing the enzyme under turnover conditions showed mechanistic insights into proton translocation coupled to electron transfer.
Studies using static samples will be discussed first, before the more technologically challenging in situ studies under turnover conditions.
Confocal microscopy analysis revealed that the thickness of biofilms under turnover conditions and non-turnover conditions was approximately 35 and 3.5 μm, respectively.
The major advantage of the technique, in a catalysis context, is that the metal centre of the catalyst can be selectively observed under turnover conditions while ignoring organic species in the system.
Applications of XAS to homogeneous catalysis in synthetic context are surprisingly few, given its potential insights on the oxidation state, electronic configuration and coordination environment of the catalyst under turnover conditions.
We have not observed PduS under turnover conditions, and therefore do not know if there is a 4-coordinate cob II)alamin species formed under such conditions.
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Reactions were performed under multiple turnover conditions where the amount of ligase was limiting (1 pmol) or under single turnover conditions where ligase was provided in excess (13.8 pmol), as indicated.
Under a turnover tax, it is taxed on both bets, or £20.
It's fair to say that small charities (under £100,000 turnover) are much less likely to be able to take on an investment.
But relations between the new board and the state advisory panel have been rocky, and the panel and the school system have labored under frequent turnover.
Further, the protein binds Zn II) and Co II) in the expected manner and shows ferroxidase activity under single turnover conditions.
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