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In the second step, a mixture of HFE-7100 (10 mL) and benzotrifluoride (6 mL) was added to dissolve PFPE COCl, followed by the addition of respective amounts of tris(hydroxymethylaminomethane) (0.025, 0.042, 0.067, or 0.084 g) under a slow argon purge.
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The gaseous Te-precursor hydrogen telluride H2Te was generated by reacting 0.2 g (0.458 mmol) Al2Te3 with 5 mL of a 0.5 M H2SO4 solution and passed through the solution under slow argon flow and vigorous stirring.
Then, the tube was cooled down to room temperature under a continuous argon flow.
All reactions were performed under a dry argon atmosphere.
All reactions were carried out under a protective argon atmosphere.
The reaction was carried out under a protective argon atmosphere using standard Schlenk techniques.
All reactions were carried out under a protective argon atmosphere by using standard Schlenk techniques.
The mixture was filtered through a sintered glass filter of medium porosity (G02) under a flowing argon blanket.
APS-mica was washed with water, dried under a stream of argon and then cured overnight and stored under argon at reduced pressure.
Hexane was removed under a stream of argon to yield the dry Pt/C catalyst powder.
The remaining solvent was dried under a stream of argon gas.
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